IndiumV3, Chine, Analysis, bibRecord, 000197

Inverted polymer solar cells integrated with small molecular electron collection layer

Identifieur interne : 000197 ( Chine/Analysis ); précédent : 000196; suivant : 000198

Inverted polymer solar cells integrated with small molecular electron collection layer

Auteurs : RBID : Pascal:13-0216867

Descripteurs français

Pascal (Inist)
- Cellule solaire organique, Combinaison diversité, Logique émetteur couplé, Addition étain, Couche ITO, Cathode, Addition césium, Spectrométrie photoélectron, Spectre photoélectron, Mesure électrique, Dopage, Niveau énergie, Alignement, Cale espacement, Eclairement, Intensité lumineuse, Optimisation, Conversion énergie, Taux conversion, Haute performance, Basse température, Oxyde d'indium, Thiophène dérivé polymère, Ester, Acide butyrique, Composé du fullerène, Carbonate de césium, Aluminium, Quinoléin-8-ol, Complexe d'aluminium, Interface, Semiconducteur type n, Matériau dopé, 8105T, 7960J, ITO, Cs2CO3.
Wicri :
- concept : Dopage, Aluminium.

English descriptors

KwdEn :
- Alignment, Aluminium, Aluminium complex, Butyric acid, Cathode, Cesium addition, Cesium carbonate, Conversion rate, Diversity combining, Doped materials, Doping, Electrical measurement, Emitter coupled logic, Energy conversion, Energy level, Ester, Fullerene compounds, High performance, ITO layers, Illumination, Indium oxide, Interface, Low temperature, Luminous intensity, Optimization, Organic solar cells, Photoelectron spectrometry, Photoelectron spectrum, Spacer, Thiophene derivative polymer, Tin addition, n type semiconductor.

Abstract

An efficient inverted polymer solar cell (PSC) is reported by integrating a small molecular electron collection layer (ECL) between indium tin oxide (ITO) cathode and the photoactive layer of blended poly(3-hexylthiophene) and [6,6]-phenyl C61 butyric acid methyl ester (P3HT:PCBM). The ECL is composed of a cesium carbonate-doped tris(8-hydroxyquinolinato) aluminum (Cs₂CO₃:Alq₃) layer. As determined by photoelectron spectroscopy and electrical measurements, the Cs₂CO₃ doping induces suitable energy level alignment at the ITO/ Cs₂CO₃:Alq₃/PCBM interface and the increase in bulk conductivity of organic ECL, which are favorable to electron extraction through Cs₂CO₃:Alq₃ to ITO cathode. In addition, optical simulation indicates that the Cs₂CO₃:Alq₃ layer can act as an optical spacer to modulate the region of highest incident light intensity within the photoactive layer, where absorption and charge dissociation are efficient. The inverted PSC with an optimized Cs₂CO₃:Alq₃ ECL exhibits a power conversion efficiency of 4.83%. The method reported here provides a facile approach to achieve high-performance inverted PSCs at low processing temperature.

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Pascal:13-0216867

Le document en format XML

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<author><name sortKey="Ueno, Nobuo" uniqKey="Ueno N">Nobuo Ueno</name>
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<author><name sortKey="Tang, Jian Xin" uniqKey="Tang J">Jian-Xin Tang</name>
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<date when="2013">2013</date>
<idno type="stanalyst">PASCAL 13-0216867 INIST</idno>
<idno type="RBID">Pascal:13-0216867</idno>
<idno type="wicri:Area/Main/Corpus">000B73</idno>
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<seriesStmt><idno type="ISSN">1566-1199</idno>
<title level="j" type="abbreviated">Org. electron. : (Print)</title>
<title level="j" type="main">Organic electronics : (Print)</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Alignment</term>
<term>Aluminium</term>
<term>Aluminium complex</term>
<term>Butyric acid</term>
<term>Cathode</term>
<term>Cesium addition</term>
<term>Cesium carbonate</term>
<term>Conversion rate</term>
<term>Diversity combining</term>
<term>Doped materials</term>
<term>Doping</term>
<term>Electrical measurement</term>
<term>Emitter coupled logic</term>
<term>Energy conversion</term>
<term>Energy level</term>
<term>Ester</term>
<term>Fullerene compounds</term>
<term>High performance</term>
<term>ITO layers</term>
<term>Illumination</term>
<term>Indium oxide</term>
<term>Interface</term>
<term>Low temperature</term>
<term>Luminous intensity</term>
<term>Optimization</term>
<term>Organic solar cells</term>
<term>Photoelectron spectrometry</term>
<term>Photoelectron spectrum</term>
<term>Spacer</term>
<term>Thiophene derivative polymer</term>
<term>Tin addition</term>
<term>n type semiconductor</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Cellule solaire organique</term>
<term>Combinaison diversité</term>
<term>Logique émetteur couplé</term>
<term>Addition étain</term>
<term>Couche ITO</term>
<term>Cathode</term>
<term>Addition césium</term>
<term>Spectrométrie photoélectron</term>
<term>Spectre photoélectron</term>
<term>Mesure électrique</term>
<term>Dopage</term>
<term>Niveau énergie</term>
<term>Alignement</term>
<term>Cale espacement</term>
<term>Eclairement</term>
<term>Intensité lumineuse</term>
<term>Optimisation</term>
<term>Conversion énergie</term>
<term>Taux conversion</term>
<term>Haute performance</term>
<term>Basse température</term>
<term>Oxyde d'indium</term>
<term>Thiophène dérivé polymère</term>
<term>Ester</term>
<term>Acide butyrique</term>
<term>Composé du fullerène</term>
<term>Carbonate de césium</term>
<term>Aluminium</term>
<term>Quinoléin-8-ol</term>
<term>Complexe d'aluminium</term>
<term>Interface</term>
<term>Semiconducteur type n</term>
<term>Matériau dopé</term>
<term>8105T</term>
<term>7960J</term>
<term>ITO</term>
<term>Cs2CO3</term>
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<keywords scheme="Wicri" type="concept" xml:lang="fr"><term>Dopage</term>
<term>Aluminium</term>
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<front><div type="abstract" xml:lang="en">An efficient inverted polymer solar cell (PSC) is reported by integrating a small molecular electron collection layer (ECL) between indium tin oxide (ITO) cathode and the photoactive layer of blended poly(3-hexylthiophene) and [6,6]-phenyl C61 butyric acid methyl ester (P3HT:PCBM). The ECL is composed of a cesium carbonate-doped tris(8-hydroxyquinolinato) aluminum (Cs<sub>2</sub>
CO<sub>3</sub>
:Alq<sub>3</sub>
) layer. As determined by photoelectron spectroscopy and electrical measurements, the Cs<sub>2</sub>
CO<sub>3</sub>
 doping induces suitable energy level alignment at the ITO/ Cs<sub>2</sub>
CO<sub>3</sub>
:Alq<sub>3</sub>
/PCBM interface and the increase in bulk conductivity of organic ECL, which are favorable to electron extraction through Cs<sub>2</sub>
CO<sub>3</sub>
:Alq<sub>3</sub>
 to ITO cathode. In addition, optical simulation indicates that the Cs<sub>2</sub>
CO<sub>3</sub>
:Alq<sub>3</sub>
 layer can act as an optical spacer to modulate the region of highest incident light intensity within the photoactive layer, where absorption and charge dissociation are efficient. The inverted PSC with an optimized Cs<sub>2</sub>
CO<sub>3</sub>
:Alq<sub>3</sub>
 ECL exhibits a power conversion efficiency of 4.83%. The method reported here provides a facile approach to achieve high-performance inverted PSCs at low processing temperature.</div>
</front>
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<fA08 i1="01" i2="1" l="ENG"><s1>Inverted polymer solar cells integrated with small molecular electron collection layer</s1>
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<fA11 i1="01" i2="1"><s1>SHI (Ai-Li)</s1>
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<fC01 i1="01" l="ENG"><s0>An efficient inverted polymer solar cell (PSC) is reported by integrating a small molecular electron collection layer (ECL) between indium tin oxide (ITO) cathode and the photoactive layer of blended poly(3-hexylthiophene) and [6,6]-phenyl C61 butyric acid methyl ester (P3HT:PCBM). The ECL is composed of a cesium carbonate-doped tris(8-hydroxyquinolinato) aluminum (Cs<sub>2</sub>
CO<sub>3</sub>
:Alq<sub>3</sub>
) layer. As determined by photoelectron spectroscopy and electrical measurements, the Cs<sub>2</sub>
CO<sub>3</sub>
 doping induces suitable energy level alignment at the ITO/ Cs<sub>2</sub>
CO<sub>3</sub>
:Alq<sub>3</sub>
/PCBM interface and the increase in bulk conductivity of organic ECL, which are favorable to electron extraction through Cs<sub>2</sub>
CO<sub>3</sub>
:Alq<sub>3</sub>
 to ITO cathode. In addition, optical simulation indicates that the Cs<sub>2</sub>
CO<sub>3</sub>
:Alq<sub>3</sub>
 layer can act as an optical spacer to modulate the region of highest incident light intensity within the photoactive layer, where absorption and charge dissociation are efficient. The inverted PSC with an optimized Cs<sub>2</sub>
CO<sub>3</sub>
:Alq<sub>3</sub>
 ECL exhibits a power conversion efficiency of 4.83%. The method reported here provides a facile approach to achieve high-performance inverted PSCs at low processing temperature.</s0>
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<s5>02</s5>
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<s5>02</s5>
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<s5>03</s5>
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<s5>03</s5>
</fC03>
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<s5>03</s5>
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<fC03 i1="04" i2="X" l="FRE"><s0>Addition étain</s0>
<s5>04</s5>
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<fC03 i1="04" i2="X" l="ENG"><s0>Tin addition</s0>
<s5>04</s5>
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<s5>04</s5>
</fC03>
<fC03 i1="05" i2="3" l="FRE"><s0>Couche ITO</s0>
<s5>05</s5>
</fC03>
<fC03 i1="05" i2="3" l="ENG"><s0>ITO layers</s0>
<s5>05</s5>
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<fC03 i1="06" i2="X" l="FRE"><s0>Cathode</s0>
<s5>06</s5>
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<s5>06</s5>
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<s5>06</s5>
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<s5>07</s5>
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<s5>07</s5>
</fC03>
<fC03 i1="07" i2="X" l="SPA"><s0>Adición cesio</s0>
<s5>07</s5>
</fC03>
<fC03 i1="08" i2="X" l="FRE"><s0>Spectrométrie photoélectron</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="ENG"><s0>Photoelectron spectrometry</s0>
<s5>08</s5>
</fC03>
<fC03 i1="08" i2="X" l="SPA"><s0>Espectrometría fotoelectrón</s0>
<s5>08</s5>
</fC03>
<fC03 i1="09" i2="X" l="FRE"><s0>Spectre photoélectron</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="ENG"><s0>Photoelectron spectrum</s0>
<s5>09</s5>
</fC03>
<fC03 i1="09" i2="X" l="SPA"><s0>Espectro fotoelectrones</s0>
<s5>09</s5>
</fC03>
<fC03 i1="10" i2="X" l="FRE"><s0>Mesure électrique</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="ENG"><s0>Electrical measurement</s0>
<s5>10</s5>
</fC03>
<fC03 i1="10" i2="X" l="SPA"><s0>Medida eléctrica</s0>
<s5>10</s5>
</fC03>
<fC03 i1="11" i2="X" l="FRE"><s0>Dopage</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="ENG"><s0>Doping</s0>
<s5>11</s5>
</fC03>
<fC03 i1="11" i2="X" l="SPA"><s0>Doping</s0>
<s5>11</s5>
</fC03>
<fC03 i1="12" i2="X" l="FRE"><s0>Niveau énergie</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="ENG"><s0>Energy level</s0>
<s5>12</s5>
</fC03>
<fC03 i1="12" i2="X" l="SPA"><s0>Nivel energía</s0>
<s5>12</s5>
</fC03>
<fC03 i1="13" i2="X" l="FRE"><s0>Alignement</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="ENG"><s0>Alignment</s0>
<s5>13</s5>
</fC03>
<fC03 i1="13" i2="X" l="SPA"><s0>Alineamiento</s0>
<s5>13</s5>
</fC03>
<fC03 i1="14" i2="X" l="FRE"><s0>Cale espacement</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="ENG"><s0>Spacer</s0>
<s5>14</s5>
</fC03>
<fC03 i1="14" i2="X" l="SPA"><s0>Calce espaciamiento</s0>
<s5>14</s5>
</fC03>
<fC03 i1="15" i2="X" l="FRE"><s0>Eclairement</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="ENG"><s0>Illumination</s0>
<s5>15</s5>
</fC03>
<fC03 i1="15" i2="X" l="SPA"><s0>Alumbrado</s0>
<s5>15</s5>
</fC03>
<fC03 i1="16" i2="X" l="FRE"><s0>Intensité lumineuse</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="ENG"><s0>Luminous intensity</s0>
<s5>16</s5>
</fC03>
<fC03 i1="16" i2="X" l="SPA"><s0>Intensidad luminosa</s0>
<s5>16</s5>
</fC03>
<fC03 i1="17" i2="X" l="FRE"><s0>Optimisation</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="ENG"><s0>Optimization</s0>
<s5>17</s5>
</fC03>
<fC03 i1="17" i2="X" l="SPA"><s0>Optimización</s0>
<s5>17</s5>
</fC03>
<fC03 i1="18" i2="X" l="FRE"><s0>Conversion énergie</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="ENG"><s0>Energy conversion</s0>
<s5>18</s5>
</fC03>
<fC03 i1="18" i2="X" l="SPA"><s0>Conversión energética</s0>
<s5>18</s5>
</fC03>
<fC03 i1="19" i2="X" l="FRE"><s0>Taux conversion</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="ENG"><s0>Conversion rate</s0>
<s5>19</s5>
</fC03>
<fC03 i1="19" i2="X" l="SPA"><s0>Factor conversión</s0>
<s5>19</s5>
</fC03>
<fC03 i1="20" i2="X" l="FRE"><s0>Haute performance</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="ENG"><s0>High performance</s0>
<s5>20</s5>
</fC03>
<fC03 i1="20" i2="X" l="SPA"><s0>Alto rendimiento</s0>
<s5>20</s5>
</fC03>
<fC03 i1="21" i2="X" l="FRE"><s0>Basse température</s0>
<s5>21</s5>
</fC03>
<fC03 i1="21" i2="X" l="ENG"><s0>Low temperature</s0>
<s5>21</s5>
</fC03>
<fC03 i1="21" i2="X" l="SPA"><s0>Baja temperatura</s0>
<s5>21</s5>
</fC03>
<fC03 i1="22" i2="X" l="FRE"><s0>Oxyde d'indium</s0>
<s5>22</s5>
</fC03>
<fC03 i1="22" i2="X" l="ENG"><s0>Indium oxide</s0>
<s5>22</s5>
</fC03>
<fC03 i1="22" i2="X" l="SPA"><s0>Indio óxido</s0>
<s5>22</s5>
</fC03>
<fC03 i1="23" i2="X" l="FRE"><s0>Thiophène dérivé polymère</s0>
<s2>NK</s2>
<s5>23</s5>
</fC03>
<fC03 i1="23" i2="X" l="ENG"><s0>Thiophene derivative polymer</s0>
<s2>NK</s2>
<s5>23</s5>
</fC03>
<fC03 i1="23" i2="X" l="SPA"><s0>Tiofeno derivado polímero</s0>
<s2>NK</s2>
<s5>23</s5>
</fC03>
<fC03 i1="24" i2="X" l="FRE"><s0>Ester</s0>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="ENG"><s0>Ester</s0>
<s5>24</s5>
</fC03>
<fC03 i1="24" i2="X" l="SPA"><s0>Ester</s0>
<s5>24</s5>
</fC03>
<fC03 i1="25" i2="X" l="FRE"><s0>Acide butyrique</s0>
<s2>NK</s2>
<s5>25</s5>
</fC03>
<fC03 i1="25" i2="X" l="ENG"><s0>Butyric acid</s0>
<s2>NK</s2>
<s5>25</s5>
</fC03>
<fC03 i1="25" i2="X" l="SPA"><s0>Butírico ácido</s0>
<s2>NK</s2>
<s5>25</s5>
</fC03>
<fC03 i1="26" i2="3" l="FRE"><s0>Composé du fullerène</s0>
<s5>26</s5>
</fC03>
<fC03 i1="26" i2="3" l="ENG"><s0>Fullerene compounds</s0>
<s5>26</s5>
</fC03>
<fC03 i1="27" i2="X" l="FRE"><s0>Carbonate de césium</s0>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="X" l="ENG"><s0>Cesium carbonate</s0>
<s5>27</s5>
</fC03>
<fC03 i1="27" i2="X" l="SPA"><s0>Cesio carbonato</s0>
<s5>27</s5>
</fC03>
<fC03 i1="28" i2="X" l="FRE"><s0>Aluminium</s0>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>28</s5>
</fC03>
<fC03 i1="28" i2="X" l="ENG"><s0>Aluminium</s0>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>28</s5>
</fC03>
<fC03 i1="28" i2="X" l="SPA"><s0>Aluminio</s0>
<s2>NC</s2>
<s2>FR</s2>
<s2>FX</s2>
<s5>28</s5>
</fC03>
<fC03 i1="29" i2="X" l="FRE"><s0>Quinoléin-8-ol</s0>
<s2>NK</s2>
<s2>FR</s2>
<s2>FF</s2>
<s5>29</s5>
</fC03>
<fC03 i1="30" i2="X" l="FRE"><s0>Complexe d'aluminium</s0>
<s5>30</s5>
</fC03>
<fC03 i1="30" i2="X" l="ENG"><s0>Aluminium complex</s0>
<s5>30</s5>
</fC03>
<fC03 i1="30" i2="X" l="SPA"><s0>Aluminio complejo</s0>
<s5>30</s5>
</fC03>
<fC03 i1="31" i2="X" l="FRE"><s0>Interface</s0>
<s5>31</s5>
</fC03>
<fC03 i1="31" i2="X" l="ENG"><s0>Interface</s0>
<s5>31</s5>
</fC03>
<fC03 i1="31" i2="X" l="SPA"><s0>Interfase</s0>
<s5>31</s5>
</fC03>
<fC03 i1="32" i2="X" l="FRE"><s0>Semiconducteur type n</s0>
<s5>32</s5>
</fC03>
<fC03 i1="32" i2="X" l="ENG"><s0>n type semiconductor</s0>
<s5>32</s5>
</fC03>
<fC03 i1="32" i2="X" l="SPA"><s0>Semiconductor tipo n</s0>
<s5>32</s5>
</fC03>
<fC03 i1="33" i2="3" l="FRE"><s0>Matériau dopé</s0>
<s5>46</s5>
</fC03>
<fC03 i1="33" i2="3" l="ENG"><s0>Doped materials</s0>
<s5>46</s5>
</fC03>
<fC03 i1="34" i2="X" l="FRE"><s0>8105T</s0>
<s4>INC</s4>
<s5>56</s5>
</fC03>
<fC03 i1="35" i2="X" l="FRE"><s0>7960J</s0>
<s4>INC</s4>
<s5>57</s5>
</fC03>
<fC03 i1="36" i2="X" l="FRE"><s0>ITO</s0>
<s4>INC</s4>
<s5>82</s5>
</fC03>
<fC03 i1="37" i2="X" l="FRE"><s0>Cs2CO3</s0>
<s4>INC</s4>
<s5>83</s5>
</fC03>
<fN21><s1>203</s1>
</fN21>
<fN44 i1="01"><s1>OTO</s1>
</fN44>
<fN82><s1>OTO</s1>
</fN82>
</pA>
</standard>
</inist>
</record>

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   |wiki=   *** parameter Area/wikiCode missing *** 
   |area=    IndiumV3
   |flux=    Chine
   |étape=   Analysis
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   |clé=     Pascal:13-0216867
   |texte=   Inverted polymer solar cells integrated with small molecular electron collection layer
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Inverted polymer solar cells integrated with small molecular electron collection layer

Inverted polymer solar cells integrated with small molecular electron collection layer

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